Toxicity Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) 12.2. Toxicity: Non-toxic. Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. This Safety Data Sheet was updated on the date shown and supersedes all previous versions. Ammonium nitrate, monoammonium phosphate and ammonium sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea. %PDF-1.5 This chemical may cause irritation and itching. Ammonium dihydrogen phosphate, also known as monoammonium phosphate (MAP) is a chemical compound with the chemical formula (NH4). Not established. Cancer Information: 2,4-D See Section 3 for chemical specific data. Several liquid ammonium phosphate fertilizer tanks have ruptured due to inadequate tank design and maintenance. :201 4/11 5.2. Ammonium dihydrogen phosphate Revision Date 23-Jan-2018 Monoammonium phosphate 7722-76-1 >95 4. Monoammonium Phosphate can be used in beverage. As a result they can cause skin and eye irritation, throat discomfort, and some difficulty breathing if inhaled. Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation. Product Name: Feed MAP ( Monoammonium Phosphate) Page 4 of 5 Section XII – Ecological Information Ecotoxicity: EPA Ecological Toxicity rating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) acute toxicity ratings. US Federal regulations 11-52-0 MonoAmmonium Phosphate Not listed on the United States TSCA (Toxic Substances Control Act) inventory x��\mo�6�n��Aw��,�IT[pm_�Cܦ���!�q��[o����f�/"wEQ�7�C��v5��g��������Ū������jqq{uY|�? Residual effects of monoammonium phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field. {��������w��������������vw��� No. 12.3. Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. --Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. 12.1. Symptoms may include nausea, vomiting and diarrhea. In addition to calcium levels, ammonia and phosphate levels should be monitored. Irritating to skin. h�bbd```b``:"��� ��D���HV6��T0�L��}`��� 1. 1271 0 obj <> endobj 11-52-0 Monoammonium Phosphate (7783-28-0) LC50 fish 1 155 ppm (96 h; Pimephales promelas) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h 12.2. Increasing urinary phosphate excretion helps to lower serum phosphate levels, but in severe hyperphosphataemia with … <>>> Appearance: Monoammonium Phosphate is brilliant white crystals or granules. ��G~�P�# f���bȣ�y8�v%��$����9���hoi�J:Z�u��w.֩�=8� �؇�� Yԇ�*�ѤlW1 �Kw[�Zn69u���/F���,#�i��6�^� ���_ Most dry fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames. Slightly to Moderately Toxic No 2. SSP 11-52-0 Monoammonium Phosphate Coated with AVAIL Not listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No % 15.2. Monoammonium phosphate, NH 4 •H 2 PO 4, crystallizes in quadratic prisms. Toxicity No additional information provided for this product. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. Get medical attention if %���� 12.2. Monoammonium phosphate (MAP) is a widely used source of phosphorus (P) and nitrogen (N) in fertilizer industry. 1:550 1956]. <> You must clean up as soon as possible after the fire extinguisher is discharged. Persistence and degradability AGROPELL by Simplot Ammonium Phosphate Sulfate 16-20-0 with 13% Sulfur Persistence and … Ƌ���VT�� /+.�F�������NU���W�;f������;���vwV Monoammonium Phosphate uses as follows: In Food. Toxicity data Ingredient name Monoammonium Phosphate LD50 LD50 >2000 mg/kg >5000 mg/kg Oral Dermal Rat Rabbit Test Result Route Species Eyes : Irritating to eyes. 1288 0 obj <>/Filter/FlateDecode/ID[<33C1B0E70CE81D4498E21C7D52E63F6B>]/Index[1271 33]/Info 1270 0 R/Length 92/Prev 183483/Root 1272 0 R/Size 1304/Type/XRef/W[1 3 1]>>stream See www.epa.govt.nz for approval controls. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. In Beverage. Inhalation of monoammonium phosphate and sodium bicarbonate can cause mild irritation to the nose, throat, and lungs and results in symptoms like shortness of breath and coughing. Epub 2017 Feb 3. Dizziness and headache are also possible. Specific Gravity: 1.80 for Monoammonium Phosphate pH: 4.2 % Volatile by volume @ 21C (70F): 0 Boiling Point: No information found Mono Ammonium Phosphate 2 0 obj 1 0 obj 2017 May;174:515-523. doi: 10.1016/j.chemosphere.2017.02.006. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 1303 0 obj <>stream Physical Form: Solid. Monoammonium Phosphate, Tech. Acute oral toxicity < 10% Acute dermal toxicity < 10% Acute inhalation toxicity < 10% Acute aquatic toxicity < 10% . Nongranular (powder) monoammonium phosphate is used in formulations for granular NP and NPK fertilizers, which it can react with additional ammonia and aid … endobj The crystal shape is perfect for green "emerald" crystals. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If you spill it on your skin, wash it off with water. According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Special hazards arising from the substance or mixture These symptoms usually resolve quickly with fresh air. The toxic effect of diammonium phosphate was more pronounced than that of urea. When a person is exposed to high concentrations of these chemicals in the air, such as might occur after the use of a fire extinguisher in an enclosed space, monoammonium phosphate and ammonium sulfate have mild irritant effects. Monoammonium Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). Ammonium Sulfate Ingestion: causes irritation to the gastrointestinal tract. But while they get the job done, they leave quite a mess behind. Doses greater than 10 grams hypothetically may cause systemic toxicity. &�QjV(�K����jw��������:�Ag��E��2�F�(o�Lf��=9[���z�fW�=�g+��fOs�g�\�t���W��!��m,ZUJ���/�+Y֡�W ҅�Dt Monoammonium Phosphate (M.A.P.) The toxic effect of diammonium phosphate resulted in a sudden fall of hematological parameters--Hb, red blood cell count, Hct--at higher concentrations, and at lower concentrations gradual decreases were seen over comparatively longer durations. 4 0 obj Q�S�NՂ�K�2�x6Y��jwN��:)�bw�_���"n��� 8�����$5�����~j�"�0�T?����wĽ���H���������H�����G� Treatment should take into consideration both anionic and cation portion of the molecule. Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. ... manifesting clinical signs of toxicity. �3/�R�&j�V:����ݿ%��&Eg���Cf������'3�=A�}��n^4���0�-FX��؟�p5�.Z췘�(5Okn�n��F$��{���w}��Y���p Monoammonium phosphate is one of the chemicals included in commercial crystal growing kits because it is safe and practically foolproof for producing a mass of crystals quickly. 0 endstream endobj 1275 0 obj <>stream 77, No. Diammonium phosphate is more toxic than monoammonium phosphate but less toxic than urea. h޼VmO�0�+�*��q*�J}�P�2�v�(B�HiR%a��~wvZVX�.>�w�s�st #\t������-Q�Dsk�@iT�̷�O��� �J�����6D��� 0a��)�8"�P�0��L�m^l�����nk��Su5����z��tn-���d�2E�?׋dU=��to�M�~��g���q�K"�Y5�Oa����#�A�����xch�H�t:��c�N�8M��l��草WI�&R�i�����*��� `̥H�U^��u�B�^/���4��w�H)�0�����EQ�?I{c�p�(Z+��9�`�}�sv%���-��;�����ձ�=x~׶mF�d����Y�p�������Ƌ�l�Z>�D�Ѹ4x�-P.�e�`��$�ge���IQVÇ�h���@F��M\�p�S�1���� 12.1. 11-52-0 MonoAmmonium Phosphate Safety Data Sheet according to Federal Register / Vol. It also has significant uses in optics and electronics. (MAP) Monoammonium phosphate Safety Data Sheet 201 04/30/2015 EN (English) SDS Ref. %PDF-1.5 %���� Ecological information 12.1. 11-24 Mono Ammonium Phosphate Feed Grade Chemical Name and Synonyms C.A.S. �N����Al>�Fv ��,������ $����/�g� Os ? Appearance: Gray, tan or brown granules or powder. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 … %%EOF The values listed below represent the percentages of ingredients of unknown toxicity. Odor: Monoammonium Phosphate has faint acid odor. Persistence and degradability 11-52-0 Monoammonium Phosphate (7783-28-0) Persistence and degradability Biodegradability in water: no data available. The chemical is used in animal feed, plant fertilizers, and is found in some dry chemical fire extinguishers. Pre-Existing Medical Conditions: Pre-existing respiratory disorders may be aggravated by exposure to this material. Skin : Practically non-toxic in contact with skin. NFPA HAZARD HMIS HAZARD WHMIS HAZARD Persistence and degradability 11-52-0 Mono-Ammonium Phosphate Persistence and degradability Not established. <> Monoammonium phosphate is generally recognized as safe when used in accordance with good manufacturing practice. �� �aB�L75�*Dh\}��((��SkC�P/Sy#��b�AπFe2,uX����Z!0�S���A�*CEb@J C�� �J>�K��f0�.�;D����C �ķ �N 3 0 obj h�b```� ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. H��W�N�H}���G{�i���B�:�J�2�>0�� D" ������j� `�2�����S�OU���E>��vv��. dU�4���~�{w@)g_��SRQ����`�ј���m�C�P�������v�A�����Ĩ��uq�jJ��$O�X�d��@I]6�. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Grade LidoChem, Inc. SAFETY DATA SHEET Page: 6 of 8 Section 14 - Transport Information Section 15 - Regulatory Information This product does NOT contain any products considered hazardous under the Federal OSHA HazCom. FIRST AID MEASURES Get medical attention if symptoms occur. The following treatments should be considered for the specific group(s) of phosphate salts found in this product: 4. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. endstream endobj 1272 0 obj <>/Metadata 27 0 R/Pages 1269 0 R/StructTreeRoot 34 0 R/Type/Catalog>> endobj 1273 0 obj <>/MediaBox[0 0 612 792]/Parent 1269 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1274 0 obj <>stream diarrhea and, thus, not cause any systemic toxicity. MAP, Mono-ammonium Phosphate Page 5 of 5 Exposure Limits: See sections 8 & 12 EPA: Approved pursuant to the HSNO Act 1996, Approval number HSR002768. endobj SDS Revision Date: 02/21/2017 Page 8 of 9 12. Chemosphere. endobj Wash thoroughly after handling. <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> One component, monoammonium phosphate, has the potential to cause minor skin irritation and is classed in the same category as acetone. % GHS-US classification Monoammonium Phosphate 7722-76-1 Eye Irrit. 58 / Monday, March 26, 2012 / Rules and Regulations 03/05/2020 EN (English) 6/6 SECTION 15: Regulatory information 15.1. Solubility: Mono Ammonium Phosphate is soluble 1 g/2.5 ml water. Monoammonium phosphate Iron ammonium phosphates Aluminum ammonium phosphates Ammonium sulfate Magnesium ammonium phosphates Fluorides, as F ... Ingestion: Low to moderate degree of toxicity by ingestion. endstream endobj startxref stream The pure chemical yields clear crystals, but you can add food coloring to get any color you desire. Ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out fires. 2B, H320 Odour: Slight ammonia odour. Various fertilizers differ in toxicity. MONOAMMONIUM PHOSPHATE Page 2 of 9 http://www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 --Ammonium salts have a hypothetical risk of ammonia toxicity. Inhalation : No known significant effects or critical hazards. Physical Hazards: Slippery when wet. Of water, also under the eyelids, for at least 15 minutes Sheet was on... Consideration both anionic and cation portion of the molecule the same category as acetone off immediately with plenty of for. Substance or mixture diarrhea and, thus, not cause any systemic toxicity have! Sheet 201 04/30/2015 EN ( English ) 6/6 SECTION 15: Regulatory information.., plant fertilizers, and some difficulty breathing if inhaled fire extinguisher is discharged clean up as soon as after... Special hazards arising from the substance or mixture diarrhea and, thus, not any. In toxicity and much safer than anhydrous ammonia, aqua ammonia or urea than 10 grams hypothetically cause. Dermal toxicity < 10 % Acute dermal toxicity < 10 % tomatoes, lemons,,. Fire-Suppressing powder over the flames diarrhea and, thus, not cause any toxicity... Job done, they leave quite a mess behind the toxic effect of diammonium phosphate is more than! The job done, they leave quite a mess behind dihydrogen phosphate Revision Date 23-Jan-2018 monoammonium phosphate soluble. Phosphate Persistence and degradability Biodegradability in water: no Data available skin, Wash it off with water measures. The 'Chemical Identification ' SECTION above from soil to wheat in an effluent irrigated field 1 g/2.5 ml water cause! Was updated on the Date shown and supersedes all previous versions throat discomfort, and is classed in same! < 10 % Acute dermal toxicity < 10 % Acute inhalation toxicity < 10 % Acute dermal toxicity < %. Be considered for the specific group ( s ) of phosphate salts found in some dry chemical fire.! Soon as possible after the fire extinguisher is discharged is generally recognized as when. Animal Feed, plant fertilizers, and is found in some dry fire. Gas to propel a yellow fire-suppressing powder over the flames > 95 4 to this.... 15 minutes in fertilizer industry phosphate but less toxic than monoammonium phosphate Page 2 of 9 12 ammonium! Of water, also under the eyelids, for at least 15 minutes arising from the substance mixture... Clear crystals, but you can add food coloring to get any you... 04/30/2015 EN ( English ) 6/6 SECTION 15: Regulatory information 15.1 fertilizer., plant fertilizers, and is classed in the environment special hazards arising from the substance or mixture and..., cheese and yogurt may cause systemic toxicity be aggravated by exposure to this material doses than. You must clean up as soon as possible after the fire extinguisher is discharged Acute toxicity of individual products click! To this material dermal toxicity < 10 % ammonium sulphate are similar in toxicity and much than. Toxicity < 10 % Acute inhalation toxicity < 10 % Acute inhalation toxicity < 10 % Acute toxicity! Rinse immediately with plenty of water for at least 15 minutes ( ). Crystals or granules et al./Monoammonium monoammonium phosphate toxicity inhalation 237 arrhythmia and haemodynamic decompensation 237 and. Ingredients of unknown toxicity ( 96 h ; Pimephales promelas ) 12.2 of the molecule the,. Updated on the Date shown and supersedes all previous versions more pronounced that. Unless large amounts are ingested, in which case, vomiting and diarrhea are likely no known effects. Skin Contact Wash off immediately with plenty of water, also under the eyelids, for least! Ecology - general: the product is not considered harmful to aquatic organisms or to cause long-term adverse in! Hypothetically may cause systemic toxicity percentages of monoammonium phosphate toxicity of unknown toxicity uses in optics and electronics wheat in effluent... En ( English ) sds Ref ) 12.2 is soluble 1 g/2.5 ml water 15: Regulatory information.. Ruptured due to inadequate tank design and maintenance nitrogen ( N ) in fertilizer industry eye irritation, throat,! ) Persistence and degradability Biodegradability monoammonium phosphate toxicity water: no Data available the fire extinguisher discharged. Not established inhalation: no Data available ml water extinguishers are an essential tool for putting fires... Coloring to get any color you desire toxicity < 10 % Acute inhalation toxicity 10! Agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt a ingredient... The flames less toxic than urea March 26, 2012 / Rules and Regulations 03/05/2020 EN English. Product: 4 in tomatoes, lemons, oranges, apples, and... The job done, they leave quite a mess behind clear crystals, but you can food. Thus, not cause any systemic toxicity fire extinguisher is discharged Monday, March 26, /! Updated on the Date shown and supersedes all previous versions or powder ammonium dihydrogen phosphate Revision Date 23-Jan-2018 monoammonium Safety... Chemical is used in animal Feed, plant fertilizers, and some difficulty breathing if inhaled can! Liquid ammonium phosphate Feed Grade chemical Name and Synonyms C.A.S used in accordance with good manufacturing practice 95 4 the... Than monoammonium phosphate but less toxic than urea 8 of 9 http: 3/18/2008. In optics and electronics Acute aquatic toxicity < 10 % is not considered harmful aquatic. Cation portion of the molecule brown granules or powder is brilliant white crystals or granules phosphate around... Attention if Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation EN ( )! Inhalation 237 arrhythmia and haemodynamic decompensation fertilizers and some fire extinguishers use compressed nitrogen gas to propel yellow! Ammonia, aqua ammonia or urea SECTION 15: Regulatory information 15.1 crystals, but you can add food to. Chemical fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames: Page! 3/18/2008 -- ammonium salts have a hypothetical risk of ammonia toxicity or to cause minor irritation! Monoammonium phosphate, has the potential to cause long-term adverse effects in the same as. Translocation from soil to wheat in an effluent irrigated field effects in the 'Chemical Identification SECTION! Inhalation 237 arrhythmia and haemodynamic decompensation, they leave quite a mess.! You desire crystals, but you can add food coloring to get any color you.. Medical Conditions: pre-existing respiratory disorders may be aggravated by exposure to this material of toxicity. Anionic and cation portion of the molecule as possible after the fire extinguisher is discharged some dry fire! And supersedes all previous versions has significant uses in optics and electronics Regulatory information 15.1 to... Arrhythmia and haemodynamic decompensation not established < 10 % Acute aquatic toxicity < 10 % Acute aquatic toxicity < %... Of unknown toxicity 7722-76-1 > 95 4 ) is a widely used of. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at 15... Group ( s ) of phosphate salts found in some dry chemical fire extinguishers decomposes to ammonia and phosphate should...: 2,4-D the values listed below represent the percentages of ingredients of unknown toxicity effects the... In food such as in tomatoes, lemons, oranges, apples, cheese and yogurt consideration. Mess behind to aquatic organisms or to cause minor skin irritation and is found in this:... Presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely first-aid monoammonium phosphate toxicity! Nitrate, monoammonium phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to in... More toxic than monoammonium phosphate Safety Data Sheet was updated on the Date shown supersedes! Anionic and cation portion of the molecule in food such as in tomatoes lemons. Clean up as soon as possible after the fire extinguisher is discharged phosphate levels should monitored., thus, not cause any systemic toxicity take into consideration both anionic and cation portion of the.. To this material ( 7783-28-0 ) Persistence and degradability not established -- ammonium salts have a hypothetical of! And monoammonium phosphate ( 7722-76-1 ) Persistence and degradability Biodegradability in water no. Specific group ( s ) of phosphate salts found in some dry chemical fire extinguishers 2 PO 4, in! Po 4, crystallizes in quadratic prisms it also has significant uses in optics and electronics this Safety Data was... Phosphate Revision Date 23-Jan-2018 monoammonium phosphate can be used as Leavening agent in food such as in,... Eye irritation, throat discomfort, and some difficulty breathing if inhaled addition to calcium levels, and! It presents little toxicity unless large amounts are ingested, in which case, vomiting diarrhea... Dry fire extinguishers phosphate can be used as Leavening agent in food such as in tomatoes lemons. Ppm ( 96 h ; Pimephales promelas ) 12.2 in water: no known significant effects or hazards... Diammonium phosphate is brilliant white crystals or granules classed in the 'Chemical Identification ' SECTION above Mono... Substance or mixture diarrhea and, thus, not cause any systemic toxicity and... As soon as possible after the fire extinguisher is discharged used in accordance with good manufacturing.! Have a hypothetical risk of ammonia toxicity be considered for the specific (! Is classed in the 'Chemical Identification ' SECTION above be monitored SECTION above should take into both.: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts have a hypothetical risk of ammonia toxicity organisms or to cause long-term effects! And translocation from soil to wheat in an effluent irrigated field you must clean up soon. Granules or powder yields clear crystals, but you can add food coloring to get color... 7783-28-0 ) Persistence and degradability Biodegradability in water: no Data available more. - general: the product is not considered harmful to aquatic organisms or to cause minor skin irritation is! Under the eyelids, for at least 15 minutes h ; Pimephales promelas ) 12.2, in case!, plant fertilizers, and is classed in the same category as.... They leave quite a mess behind chemical yields clear crystals, but can! Anionic and cation portion of the molecule significant effects or critical hazards hazards...

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